RAPID SYNTHESIS AND PROPERTIES OF FEVO4, ALVO4, YVO4, AND EU3-DOPED YVO4()

Citation
S. Ekambaram et Kc. Patil, RAPID SYNTHESIS AND PROPERTIES OF FEVO4, ALVO4, YVO4, AND EU3-DOPED YVO4(), Journal of alloys and compounds, 217(1), 1995, pp. 104-107
Citations number
18
Categorie Soggetti
Chemistry Physical","Metallurgy & Metallurigical Engineering","Material Science
ISSN journal
09258388
Volume
217
Issue
1
Year of publication
1995
Pages
104 - 107
Database
ISI
SICI code
0925-8388(1995)217:1<104:RSAPOF>2.0.ZU;2-4
Abstract
Fine particle FeVO4, AlVO4, YVO4 and Y0.95Eu0.05VO4 have been prepared by the combustion of aqueous solutions containing corresponding metal nitrate, ammonium metavanadate, ammonium nitrate and 3-methyl-5-pyraz olone. The solutions containing the redox mixtures, when rapidly heate d at 370 degrees C, ignite and undergo self-propagating, gas-producing , exothermic reactions to yield fine particle metal vanadates. Formati on of crystalline vanadates was confirmed by powder X-ray diffraction patterns, Al-27 nuclear magnetic resonance, IR and fluorescence spectr a.