Sulfomethylated phenolic resin (SMP) is a drilling mud additive having
good fluid loss and dispersion characters and may be resistant to the
action of high temperature and high salt frequently encountered in we
ll drilling, especially in deep wells. SMP is one kind of polyelectrol
yte. There are dissociable groups (-CH2SO3-Na+) along the chain of SMP
. The conformations and properties of SMP in solution are affected gre
atly due to electrostatic attraction and repulsion. From the experimen
tal results of viscosities and fluorescence spectra of polyelectrolyte
SMP in pure water and aqueous solutions containing added salt, the ef
fects of added salt on molecular conformations of SMP in aqueous solut
ion and properties of reducing fluid loss of water base drilling mud a
re discussed. (C) 1995 John Wiley and Sons, Inc.