SYNTHESES OF CYCLOHEXENONE DERIVATIVES BY THE RUTHENIUM COMPLEX-CATALYZED REACTIONS OF ALLYLIC COMPOUNDS WITH BETA-KETO-ESTERS

Authors
ZHANG SW MITSUDO T KONDO T WATANABE Y
Citation
Sw. Zhang et al., SYNTHESES OF CYCLOHEXENONE DERIVATIVES BY THE RUTHENIUM COMPLEX-CATALYZED REACTIONS OF ALLYLIC COMPOUNDS WITH BETA-KETO-ESTERS, Journal of organometallic chemistry, 485(1-2), 1995, pp. 55-62
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
485
Issue
1-2
Year of publication
1995
Pages
55 - 62
Database
ISI
SICI code
0022-328X(1995)485:1-2<55:SOCDBT>2.0.ZU;2-S
Abstract
Allylic compounds such as allyl alcohols and allylamines react with tw o equivalent moles of acetoacetates in the presence of a catalytic amo unt of Ru(cod)(cot) (cod = cycloocta-1,5-diene; cot = cycloocta-1,3,5- triene) at 100 degrees C for 5 h to give cyclohexenone derivatives in high yields.