Citation
Hg. Ang et al., TRIOSMIUM CARBONYL CLUSTER DERIVATIVES CONTAINING PENTAMERIC PHENYL CYCLOPOLYPHOSPHINE, Journal of organometallic chemistry, 485(1-2), 1995, pp. 10-13
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
0022328X
Volume
485
Issue
1-2
Year of publication
1995
Pages
10 - 13
Database
ISI
SICI code
0022-328X(1995)485:1-2<10:TCCDCP>2.0.ZU;2-H
Abstract
The reactions of the pentaphenylcyclopentaphosphine with [Os-3(CO)(10)
(NCCH3)(2)] afforded a pair of inversion isomers, (1) and (2). [Os-3(C
O)(11)(C6H5P)(5)] (3) and [{Os-3(CO)(11)}(2)(C6H5P)(5)] (4) were obtai
ned by the treatment of the same ligand with [Os-3(CO)(11)(NCCH3)]. Th
e four new triosmium clusters have been shown by X-ray crystallography
to contain an intact cyclopolyphospine ring in each case.