[(2,2-BIS-ETA-CYCLOPENTADIENYL)PROPANE]-MOLYBDENUM AND A-[(2,2-BIS-ETA-CYCLOPENTADIENYL)PROPANE]-TUNGSTEN CHEMISTRY AND RELATED STUDIES

Citation
L. Labella et al., [(2,2-BIS-ETA-CYCLOPENTADIENYL)PROPANE]-MOLYBDENUM AND A-[(2,2-BIS-ETA-CYCLOPENTADIENYL)PROPANE]-TUNGSTEN CHEMISTRY AND RELATED STUDIES, Journal of organometallic chemistry, 485(1-2), 1995, pp. 18-21
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
485
Issue
1-2
Year of publication
1995
Pages
18 - 21
Database
ISI
SICI code
0022-328X(1995)485:1-2<18:[AA>2.0.ZU;2-L
Abstract
The compounds [M(eta-C5H4-CMe(2) mu-C5H4)X(2)] (where M = Mo and X(2) = H-2, Cl-2, Me(2), PhH; M = W and X(2) = H-2, Cl-2, Me(2), Me(PhCO(2 )), MeH) and [Mo(eta-C5H4C(CH2)(4)-eta-C5H4)X(2)] (X = H, Cl) are des cribed. For the complexes marked with an asterisk the crystal structur es are reported. These ansa-bridged compounds exhibit substantially di fferent reactivities from those of the unbridged analogues.