A CONVENIENT ELECTROSYNTHESIS OF NEW COMPLEXES [SN(CO(CO)(3)PR(3))(4)] AND THEIR SPECTROSCOPIC CHARACTERIZATION

Authors
RIETHER KB PELLEGRINI S MORTREUX A MONFLIER E
Citation
Kb. Riether et al., A CONVENIENT ELECTROSYNTHESIS OF NEW COMPLEXES [SN(CO(CO)(3)PR(3))(4)] AND THEIR SPECTROSCOPIC CHARACTERIZATION, Journal of organometallic chemistry, 486(1-2), 1995, pp. 123-127
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
486
Issue
1-2
Year of publication
1995
Pages
123 - 127
Database
ISI
SICI code
0022-328X(1995)486:1-2<123:ACEONC>2.0.ZU;2-Y
Abstract
New complexes [Sn{Co(CO)(3)PR(3)}], which have been identified by FTIR , mass spectroscopy, P-31{H-1} and Sn-119{H-1} NMR, were obtained easi ly in high yield (70-80%) by electroreduction of a series of water-sol uble or water-insoluble complexes [Co-2(CO)(6)(PR(3))(2)]. The mechani stic aspects of the synthesis are discussed.