STUDY OF HALOGEN EXCHANGES IN [2-(BROMOCHLOROPHENYLSTANNYL)VINYL]-1-CYCLOHEXANOL BY 2D SN-119 EXSY NMR

Authors
KAYSER F BIESEMANS M FU FX PAN HA GIELEN M WILLEM R
Citation
F. Kayser et al., STUDY OF HALOGEN EXCHANGES IN [2-(BROMOCHLOROPHENYLSTANNYL)VINYL]-1-CYCLOHEXANOL BY 2D SN-119 EXSY NMR, Journal of organometallic chemistry, 486(1-2), 1995, pp. 263-265
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
486
Issue
1-2
Year of publication
1995
Pages
263 - 265
Database
ISI
SICI code
0022-328X(1995)486:1-2<263:SOHEI[>2.0.ZU;2-Z
Abstract
The halogen exchange reactions at equilibrium of (Z)-1-[2-(bromochloro phenylstannyl)vinyl] were studied by two-dimensional Sn-119 exchange N MR spectroscopy (2D Sn-119 EXSY NMR). A single halogen exchange mechan ism was found from a quantitative matrix analysis of the data.