THE FIRST CHIRAL RACEMIC FISCHER-TYPE AMINOCARBENE COMPLEX BEARING A C-2 SYMMETRY AMINE - STEREOCHEMICAL CHARACTERISTICS AND APPLICATION TOMICHAEL ADDITION-REACTIONS

Authors
BALDOLI C DELBUTTERO P LICANDRO E MAIORANA S PAPAGNI A ZANOTTIGEROSA A
Citation
C. Baldoli et al., THE FIRST CHIRAL RACEMIC FISCHER-TYPE AMINOCARBENE COMPLEX BEARING A C-2 SYMMETRY AMINE - STEREOCHEMICAL CHARACTERISTICS AND APPLICATION TOMICHAEL ADDITION-REACTIONS, Journal of organometallic chemistry, 486(1-2), 1995, pp. 279-282
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
486
Issue
1-2
Year of publication
1995
Pages
279 - 282
Database
ISI
SICI code
0022-328X(1995)486:1-2<279:TFCRFA>2.0.ZU;2-S
Abstract
The synthesis of imethyl)morpholinocarbene]pentacarbonylchromium(0) co mplex (3) is reported, together with the stereoselective Michael addit ion of the conjugate base of complex 3 to enones.