RADIOLYTIC SYNTHESIS AND CHARACTERIZATION OF [RU-II(ACAC)(2)(CO)L] (L=MEOH, ETOH OR PR(I)OH)

Authors
REMITA H BRIK ME DARAN JC DELCOURT MO
Citation
H. Remita et al., RADIOLYTIC SYNTHESIS AND CHARACTERIZATION OF [RU-II(ACAC)(2)(CO)L] (L=MEOH, ETOH OR PR(I)OH), Journal of organometallic chemistry, 486(1-2), 1995, pp. 283-285
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
486
Issue
1-2
Year of publication
1995
Pages
283 - 285
Database
ISI
SICI code
0022-328X(1995)486:1-2<283:RSACO[>2.0.ZU;2-P
Abstract
The radiolysis of alcoholic solutions of [Ru-III(acac)(3)] under CO le ads selectively to the formation of a new complex [Ru-II(acac)(2)(CO)L ] (L = MeOH, EtOH or (PrOH)-O-i). [Ru-II(acac)(2)(CO)MeOH] 1 has been characterized by microanalysis, UV-visible, IR, C-13-NMR and H-1-NMR s pectroscopies. The X-ray structural study of the complex 1 is also rep orted.