SYNTHESIS AND CHARACTERIZATION OF NOVEL BISMUTH PHOSPHONATES - X-RAY CRYSTAL-STRUCTURE OF BI(O3PC2H4CO2).H2O

Authors
JANVIER P DRUMEL S PIFFARD Y BUJOLI B
Citation
P. Janvier et al., SYNTHESIS AND CHARACTERIZATION OF NOVEL BISMUTH PHOSPHONATES - X-RAY CRYSTAL-STRUCTURE OF BI(O3PC2H4CO2).H2O, Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie, 320(1), 1995, pp. 29-35
Citations number
18
Categorie Soggetti
Multidisciplinary Sciences
Journal title
Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie → ACNP
ISSN journal
12518069
Volume
320
Issue
1
Year of publication
1995
Part
1
Pages
29 - 35
Database
ISI
SICI code
1251-8069(1995)320:1<29:SACONB>2.0.ZU;2-C
Abstract
2-carboxyethylphosphonic acid reacts with bismuth nitrate in water and organic solvents to give Bi(O3PC2H4CO2).H2O 1, and HBi(O3PC2H4CO2H)2 2. Compound 1 crystallizes in the space group P2(1)/c, a = 8.820(3) an gstrom, b = 11.830(3) angstrom, c = 7.039(1) angstrom, beta = 95.28(2) -degrees, and has an original layered structure, pillared by the PO3 a nd CO2 moieties.