Jr. Anacona, NEW ROTATIONAL TRANSITIONS IN (N32S)-N-14-S-32 (X2-PI(3 2))(UPSILON=0,1) DETECTED BY LASER MAGNETIC-RESONANCE AT 561.3-MU-M AND 618.4-MU-M/, SPECT ACT A, 51(1), 1995, pp. 39-44
New far infrared laser magnetic resonance (FIR LMR) spectra of N-14-S-
32(2II3/2) have been observed at 561.3 and 618.4 mum using DCOOD and C
2H3Br optically pumped lasers, respectively. In the first case, the sp
ectrum can be assigned to the rotational transition J = 10.5 --> 11.5
of the ground vibrational state. In the second case, the spectrum can
be attributed to the transition J = 9.5 --> 10.5 in the first excited
vibrational state. This is the first detection by LMR of N-14S-32 vibr
ationally excited. The agreement between the theory and experiment con
firms the spectroscopic assignments.