NEW ROTATIONAL TRANSITIONS IN (N32S)-N-14-S-32 (X2-PI(3 2))(UPSILON=0,1) DETECTED BY LASER MAGNETIC-RESONANCE AT 561.3-MU-M AND 618.4-MU-M/

Authors
Citation
Jr. Anacona, NEW ROTATIONAL TRANSITIONS IN (N32S)-N-14-S-32 (X2-PI(3 2))(UPSILON=0,1) DETECTED BY LASER MAGNETIC-RESONANCE AT 561.3-MU-M AND 618.4-MU-M/, SPECT ACT A, 51(1), 1995, pp. 39-44
Citations number
31
Categorie Soggetti
Spectroscopy
ISSN journal
13861425
Volume
51
Issue
1
Year of publication
1995
Pages
39 - 44
Database
ISI
SICI code
1386-1425(1995)51:1<39:NRTI
Abstract
New far infrared laser magnetic resonance (FIR LMR) spectra of N-14-S- 32(2II3/2) have been observed at 561.3 and 618.4 mum using DCOOD and C 2H3Br optically pumped lasers, respectively. In the first case, the sp ectrum can be assigned to the rotational transition J = 10.5 --> 11.5 of the ground vibrational state. In the second case, the spectrum can be attributed to the transition J = 9.5 --> 10.5 in the first excited vibrational state. This is the first detection by LMR of N-14S-32 vibr ationally excited. The agreement between the theory and experiment con firms the spectroscopic assignments.