MONOMER CHAIN CROSS-TRANSFER CONSTANTS AND CROSS TERMINATION FACTOR EVALUATIONS ON STYRENE-ACRYLONITRILE COPOLYMERIZATION

Authors
MENDIZABAL E VELAZQUEZ S GONZALEZ V JASSO CF
Citation
E. Mendizabal et al., MONOMER CHAIN CROSS-TRANSFER CONSTANTS AND CROSS TERMINATION FACTOR EVALUATIONS ON STYRENE-ACRYLONITRILE COPOLYMERIZATION, Polymer engineering and science, 35(2), 1995, pp. 195-201
Citations number
22
Categorie Soggetti
Polymer Sciences","Engineering, Chemical
Journal title
Polymer engineering and science → ACNP
ISSN journal
00323888
Volume
35
Issue
2
Year of publication
1995
Pages
195 - 201
Database
ISI
SICI code
0032-3888(1995)35:2<195:MCCCAC>2.0.ZU;2-D
Abstract
Using low conversion bulk copolymerization experimental data and the a pparent rate constant model, the monomer chain cross-transfer rate con stants and the cross-termination coefficient were evaluated. It was fo und that the dependence of the cross-termination coefficient on compos ition is a function of initiator efficiency and that monomer chain cro ss-transfer rate constant are relevant for the theoretical estimation of the molecular weights and molecular weight distributions.