ATMOSPHERIC CHEMISTRY OF FNO AND FNO2 - REACTIONS OF FNO WITH O-3, O(P-3), HO2, AND HCL AND THE REACTION OF FNO2 WITH O-3

Authors
WALLINGTON TJ SCHNEIDER WF SZENTE JJ MARICQ MM NIELSEN OJ SEHESTED J
Citation
Tj. Wallington et al., ATMOSPHERIC CHEMISTRY OF FNO AND FNO2 - REACTIONS OF FNO WITH O-3, O(P-3), HO2, AND HCL AND THE REACTION OF FNO2 WITH O-3, Journal of physical chemistry, 99(3), 1995, pp. 984-989
Citations number
24
Categorie Soggetti
Chemistry Physical
Journal title
Journal of physical chemistry → ACNP
ISSN journal
00223654
Volume
99
Issue
3
Year of publication
1995
Pages
984 - 989
Database
ISI
SICI code
0022-3654(1995)99:3<984:ACOFAF>2.0.ZU;2-L
Abstract
Upper limits for the rate constants of the following gas phase reactio ns have been determined at 296 K: k(FNO+O-3) < 3 x 10(-18), k(FNO+O(P- 3)) < 5 x 10(-13), k(FNO+HO2) < 3 x 10(-12), k(FNO+HCl) < 5 x 10(-18), and k(FNO2+O-3) < 8 x 10(-19) cm(3) molecule(-1) s(-1). These reactio ns can be ruled out as chain or sink reactions of FNO in the atmospher e. The implications for the atmospheric chemistry of FNO are discussed .