SKELETAL ISOMERIZATION OF 1-BUTENE ON 10-MEMBER RING ZEOLITE CATALYSTS

Authors
OYOUNG CL PELLET RJ CASEY DG UGOLINI JR SAWICKI RA
Citation
Cl. Oyoung et al., SKELETAL ISOMERIZATION OF 1-BUTENE ON 10-MEMBER RING ZEOLITE CATALYSTS, Journal of catalysis, 151(2), 1995, pp. 467-469
Citations number
10
Categorie Soggetti
Chemistry Physical
Journal title
Journal of catalysis → ACNP
ISSN journal
00219517
Volume
151
Issue
2
Year of publication
1995
Pages
467 - 469
Database
ISI
SICI code
0021-9517(1995)151:2<467:SIO1O1>2.0.ZU;2-8
Abstract
Effects of zeolite pore structure on skeletal isomerization of 1-buten es are investigated. Three 10-member ring zeolites, ferrierite, ZSM-23 , and ZSM-5, are studied and compared. Results show that ferrierite, w ith intersecting 10-MR and 8-MR channels, has better isomerization act ivity than ZSM-23, with monodirectional 10-MR channels, ZSM-5 with two intersecting 10-MR channels is not a selective isomerization catalyst . (C) 1995 Academic Press, Inc.