PALLADIUM(II) CATALYZED OXIDATION OF ALLYL ALCOHOL BY MANGANESE(III) IN AQUEOUS SULFURIC-ACID

Authors
MORAB VA NANDIBEWOOR ST
Citation
Va. Morab et St. Nandibewoor, PALLADIUM(II) CATALYZED OXIDATION OF ALLYL ALCOHOL BY MANGANESE(III) IN AQUEOUS SULFURIC-ACID, Reaction kinetics and catalysis letters, 53(1), 1994, pp. 25-31
Citations number
13
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
53
Issue
1
Year of publication
1994
Pages
25 - 31
Database
ISI
SICI code
0133-1736(1994)53:1<25:PCOOAA>2.0.ZU;2-Z
Abstract
The palladium(II) catalyzed oxidation of allyl alcohol by manganese(II I) in acid medium is assumed to go via substrate-catalyst complex form ation followed by the interaction of oxidant and complex in the rate-d etermining step. The rates exhibit fractional order in allyl alcohol a nd first order each in [Mn(III)] and [W(II)]. The reaction constants i nvolved in the mechanism are determined.