THE 1,4-CYCLOHEXANEDIONE-BROMATE-ACID OSCILLATORY SYSTEM .1. ITS ORGANIC-CHEMISTRY

Authors
KURINCSORGEI K SZALAI I MOLNARPERL I KOROS E
Citation
K. Kurincsorgei et al., THE 1,4-CYCLOHEXANEDIONE-BROMATE-ACID OSCILLATORY SYSTEM .1. ITS ORGANIC-CHEMISTRY, Reaction kinetics and catalysis letters, 53(1), 1994, pp. 115-121
Citations number
13
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
53
Issue
1
Year of publication
1994
Pages
115 - 121
Database
ISI
SICI code
0133-1736(1994)53:1<115:T1OS.I>2.0.ZU;2-E
Abstract
The organic chemistry of the 1,4-cyclohexanedione (CHD)-bromate-sulfur ic acid oscillatory system has been revealed by following the reaction of 1,4-CHD with bromate using a GC/MS technique. We could identify 1, 4-dihydroxybenzene as an intermediate, 1,4-benzoquinone as the main ox idation, and mono- and dibromocyclohexanedione as the main bromination products. Acid bromate does not cleave the alicyclic ring.