ACID CATALYSIS IN THE N-BROMOSUCCINIMIDE-PROPARGYL ALCOHOL REACTION

Authors
KARUNAKARAN C ISMAIL J MANNAN SM
Citation
C. Karunakaran et al., ACID CATALYSIS IN THE N-BROMOSUCCINIMIDE-PROPARGYL ALCOHOL REACTION, Reaction kinetics and catalysis letters, 53(1), 1994, pp. 191-196
Citations number
10
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
53
Issue
1
Year of publication
1994
Pages
191 - 196
Database
ISI
SICI code
0133-1736(1994)53:1<191:ACITNA>2.0.ZU;2-K
Abstract
The reaction of N-bromosuccinimide (NBS) with propargyl alcohol in aqu eous acidic medium is hydroxybromination. It is first order with respe ct to NBS, propargyl alcohol and H+, and inverse first order with resp ect to succinimide. The kinetic results point to solvated bromonium io n as the reactive species.