AN ORGANOIMIDO DERIVATIVE OF THE HEXATUNGSTATE CLUSTER - PREPARATION AND STRUCTURE OF [W6O18(NAR)](2-) (AR=2,6-(I-PR)(2)C6H3)

Authors
MOHS TR YAP GPA RHEINGOLD AL MAATTA EA
Citation
Tr. Mohs et al., AN ORGANOIMIDO DERIVATIVE OF THE HEXATUNGSTATE CLUSTER - PREPARATION AND STRUCTURE OF [W6O18(NAR)](2-) (AR=2,6-(I-PR)(2)C6H3), Inorganic chemistry, 34(1), 1995, pp. 9-10
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
1
Year of publication
1995
Pages
9 - 10
Database
ISI
SICI code
0020-1669(1995)34:1<9:AODOTH>2.0.ZU;2-1
Abstract
A functionalized hexatungstate cluster bearing an organoimido ligand [ W6O18(NAr)](2-), 1 (Ar=2,6-(i-Pr)(2)C6H3), is produced in the reaction of ArNCO with [Bu(4)N](2)[WO4]. 1 is a hydrolytically stable yellow m aterial (lambda(max)=292 nm) that can be reduced to the corresponding trianion. Comparisons are drawn between 1, its Mo analogue, and its [W 6O19](2-) relative.