NEW BONDING MODE FOR CYANOACETYLENE - A TUNGSTEN(II) FLUORIDE CARBONYL COMPLEX IN WHICH CYANOACETYLENE SERVES AS A 4-ELECTRON DONOR ALKYNE LIGAND

Authors
KIPLINGER JL ARIF AM RICHMOND TG
Citation
Jl. Kiplinger et al., NEW BONDING MODE FOR CYANOACETYLENE - A TUNGSTEN(II) FLUORIDE CARBONYL COMPLEX IN WHICH CYANOACETYLENE SERVES AS A 4-ELECTRON DONOR ALKYNE LIGAND, Inorganic chemistry, 34(1), 1995, pp. 399-401
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
1
Year of publication
1995
Pages
399 - 401
Database
ISI
SICI code
0020-1669(1995)34:1<399:NBMFC->2.0.ZU;2-C
Abstract
The synthesis, characterization, and reactivity of a new tungsten(II) fluoride carbonyl complex in which cyanoacetylene serves as a four-ele ctron donor alkyne ligand is reported. X-ray crystallography revealed that the complex exhibits unusual N=C-C=C-H...F-W hydrogen bonding whi ch controls the solid state packing of this molecule.