MOLECULAR-STRUCTURE AND ELECTRONIC-PROPERTIES OF OXOMOLYBDENUM(V) CATECHOLATE COMPLEXES

Authors
BASU P BRUCK MA LI Z DHAWAN IK ENEMARK JH
Citation
P. Basu et al., MOLECULAR-STRUCTURE AND ELECTRONIC-PROPERTIES OF OXOMOLYBDENUM(V) CATECHOLATE COMPLEXES, Inorganic chemistry, 34(1), 1995, pp. 405-407
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
1
Year of publication
1995
Pages
405 - 407
Database
ISI
SICI code
0020-1669(1995)34:1<405:MAEOOC>2.0.ZU;2-D
Abstract
A series of mononuclear catecholato complexes of general formula LMoO( cat) (L = hydrotris(3,5-dimethyl-1-pyrazolyl)borate) have been prepare d and characterized by cyclic voltammetry, IR, UV/vis, and EPR spectro scopy. The potential of the Mo(V/IV) redox couple is sensitive to the catechol substituents, but the nearly axial EPR parameters are primari ly governed by the coordination environment about the metal and are si milar for all of the compounds.