ORTHOAMIDES .48. REACTIONS OF AN AZAVINYLOGUE AMINALESTER [2-AZA-1,3-BIS(DIMETHYLAMINO)3-METHOXY-1-PROPEN] WITH CH2-ACIDIC COMPOUNDS

Citation
W. Kantlehner et M. Hauber, ORTHOAMIDES .48. REACTIONS OF AN AZAVINYLOGUE AMINALESTER [2-AZA-1,3-BIS(DIMETHYLAMINO)3-METHOXY-1-PROPEN] WITH CH2-ACIDIC COMPOUNDS, Bulletin des Societes chimiques belges, 103(12), 1994, pp. 697-703
Citations number
31
Categorie Soggetti
Chemistry
ISSN journal
00379646
Volume
103
Issue
12
Year of publication
1994
Pages
697 - 703
Database
ISI
SICI code
0037-9646(1994)103:12<697:O.ROAA>2.0.ZU;2-I
Abstract
Condensation reactions of azavinylogue orthoamides 5a and 69 with CH2- acidic compounds are described. Reaction products are formylated - or azavinylogue formylated compounds 8 and 9 resp. The condensation react ions of 5a can be enhanced by addition of trimethyl berate. Under thes e conditions the formylations reaction-leading to compounds of type 8 - is preferred.