The role of urban plumes in the exposure of suburban/rural areas to po
llution by ozone is discussed, and literature on direct measurement of
ozone within plumes reviewed. There is a virtual absence of reports o
f ozone destruction within a NOx-rich urban plume and reasons are give
n for this gap in the current published data. These negative ozone inc
rements are important because the particular air quality problems enco
untered downwind of a city will depend on its character as a source or
sink of ozone. Simple plume reconstruction methods are used to verify
and extend data from measurements in the London plume. There is an op
timum time for air-parcel release with respect to increased plume ozon
e, and a change in the typical diurnal variation of ground-level ozone
concentrations when the receptor site is situated within an urban plu
me. On a surface constructed from air parcel emission times and times
travelled downwind of London, a major peak in plume ozone increment is
observed 6-8 h downwind of a post rush-hour release in the urban cent
re. A secondary maximum in the surface is also apparent for air parcel
s 2-3 h after release in the early afternoon. These are not the emissi
on and travel times usually adopted in modelling studies of the urban
plume from London. Sites in the urban plume are also found to have a s
tatistically different diurnal variation compared to rural/suburban si
tes which are not influenced by the plume. This is due to the titratio
n of ozone mixing into the plume from aloft by plume NO.