CALCULATION OF OUTER HELMHOLTZ POTENTIAL AT MERCURY AS A FUNCTION OF TEMPERATURE AND CONCENTRATION OF AQUEOUS SODIUM-FLUORIDE SOLUTIONS

Authors
KIROWAEISNER E TZUR D SCHWARZ M
Citation
E. Kirowaeisner et al., CALCULATION OF OUTER HELMHOLTZ POTENTIAL AT MERCURY AS A FUNCTION OF TEMPERATURE AND CONCENTRATION OF AQUEOUS SODIUM-FLUORIDE SOLUTIONS, Journal of electroanalytical chemistry [1992], 381(1-2), 1995, pp. 11-14
Citations number
11
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
381
Issue
1-2
Year of publication
1995
Pages
11 - 14
Database
ISI
SICI code
Abstract
Potentials of the outer Helmholtz plane, phi(2), at mercury as functio n of electrode potential and temperature are calculated on the basis o f the Gouy-Chapman theory using Grahame's data for surface charge and capacitance in aqueous NaF solutions. An empirical equation for calcul ating phi(2) at negative rational potential is presented. Grahame's or iginal data of surface charge and capacitance are summarized in ASCII files on floppy disk.