OXIDATION OF COPPER(I), SILVER(I), AND MERCURY(II) METHYLACETYLIDES IN AQUEOUS-SOLUTIONS

Authors
HOAN HM BRAILOVSKII SM TEMKIN ON
Citation
Hm. Hoan et al., OXIDATION OF COPPER(I), SILVER(I), AND MERCURY(II) METHYLACETYLIDES IN AQUEOUS-SOLUTIONS, Kinetics and catalysis, 35(6), 1994, pp. 820-823
Citations number
16
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
35
Issue
6
Year of publication
1994
Pages
820 - 823
Database
ISI
SICI code
0023-1584(1994)35:6<820:OOCSAM>2.0.ZU;2-0
Abstract
A dialkyne species is found to be the primary product of Cu(I) and Ag( I) methylacetylide oxidation with copper halides, while the oxidation of Hg(II) methylacetylide yields a haloalkyne entity as a primary prod uct. Various oxidants are arranged in a series by relative reactivity in the reactions involving Cu(I) and Ag(I) methylacetylides. The mecha nism for the oxidative transformations of metal alkynyl complexes is d iscussed.