Spectroscopic ellipsometry (SE) has proven to be a very powerful diagn
ostic for thin film characterization, but the results of SE experiment
s must first be compared with calculations to determine thin film para
meters such as film thickness and optical functions. This process requ
ires four steps. (1) The quantities measured must be specified and the
equivalent calculated parameters identified. (2) The film structure m
ust be modeled, where the number of films is specified and certain cha
racteristics of each layer specified, such as whether or not the film
is isotropic or anisotropic, homogeneous or graded. (3) The optical fu
nctions of each layer must be specified or parameterized. (4) The data
must be compared with the calculated spectra, where a quantifiable fi
gure of merit is used for the comparison. The last step is particularl
y important because without it, no ''goodness of fit'' parameter is ca
lculated and one does not know whether or not the calculated spectrum
fits the data.