Latex particles with divergent characteristics, Like surface morpholog
y, charge, and functional groups, were synthesized. In particular, hyd
roxyl functions were investigated in different surroundings. The techn
ique of electrophoretic fingerprinting was applied to determine and il
lustrate the complex colloidal behavior in aqueous medium under variat
ion of pH and ionic strength. BD-profiles of electrophoretic mobility
showed a separation of our latex particle types into two classes: (a)
mobility is dominated by a salt dependence, and (b) pH dependence domi
nates the electrophoretic behavior. Independent surface charge density
data, from streaming potential or flocculation measurements, were hel
pful in interpreting the electrophoresis characteristics.