Electrooxidative polymerization of 3-ethylpyrrole on gold electrodes m
odified with spontaneously adsorbed monolayers (SAMs) of alkanethiols
bearing 3-substituted pyrroles such as 3-(11-mercaptoundecyl)pyrrole,
4-(3-pyrrolyl)butyl 11-mercaptoundecanoate, and 11-mercaptoundecyl 3-p
yrrolylacetate affords dense, robust, and extremely adhesive films of
poly(3-ethylpyrrole). In the absence of monomer in contacting solution
, the surface-confined monolayers are subject to irreversible electroo
xidation. Scanning electron microscopy indicates that the presence of
these monolayers enhances the morphological packing in films of poly(3
-ethylpyrrole) compared to that of films deposited on unmodified elect
rodes. The conductivity of these films is enhanced as a consequence of
this change in morphology.