Second harmonic generation in gallium-lanthanum-sulphide (Ga:La:S) and
germanium sulphide + Ga:La:S glasses is investigated. It is shown tha
t microcrystals of Ga:La:S and alpha phase of gallium-sulphide (alpha-
Ga2S3), whose presence in the glass matrix is revealed by energy dispe
rsive spectroscopy and x-ray diffraction analysis, are responsible for
the frequency doubling process. (C) 1997 American Institute of Physic
s.