Welding trials and surface tension measurements have been carried out
on 304 stainless steels with sulfur (S) contents between 20 and 100 pp
m. Surface tension measurements, determined by the levitated drop meth
od, indicated that the temperature coefficient of surface tension (dga
mma/dT) changed from negative to positive values at S contents exceedi
ng approximately 50 ppm. Strips with a thickness of approximately 1 mm
were GTA welded on both single-electrode, small-scale and multi-elect
rode industrial-scale units. Welding speeds of 1 to 2 m min-1 were use
d on the small-scale unit and up to 5 m min-1 on the industrial unit.
The weld penetration was found to increase, for both full and partial
penetration welds, with 1) increasing sulfur contents; and 2) increasi
ng linear energy (i.e., current x voltage/welding speed). On the small
scale-unit markedly higher penetration was observed in heats with S c
ontents > 60 ppm. But the influence of S contents was only of minor im
portance for welds obtained on the industrial unit. It was found that
the similar weld geometry could be obtained for both low (less-than-or
-equal-to 60 ppm) and high (> 60 ppm) sulfur contents by careful adjus
tment of welding parameters. The observed changes in weld geometry are
consistent with the proposition that the fluid flow in the weld pool
is dominated by thermocapillary (Marangoni) forces during the GTA weld
ing of thin strips.