DIRECT CONVERSION OF P-METHOXYBENZYL ETHERS INTO SILYL-PROTECTED ALCOHOLS BY THE ACTION OF TRIALKYLSILYL TRIFLUOROMETHANESULFONATE AND TRIETHYLAMINE

Authors
ORIYAMA T YATABE K KAWADA Y KOGA G
Citation
T. Oriyama et al., DIRECT CONVERSION OF P-METHOXYBENZYL ETHERS INTO SILYL-PROTECTED ALCOHOLS BY THE ACTION OF TRIALKYLSILYL TRIFLUOROMETHANESULFONATE AND TRIETHYLAMINE, Synlett, (1), 1995, pp. 45-46
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
1
Year of publication
1995
Pages
45 - 46
Database
ISI
SICI code
0936-5214(1995):1<45:DCOPEI>2.0.ZU;2-V
Abstract
The combined use of t-butyldimethylsilyl trifluoromethanesulfonate and triethylamine cleaves readily p- or o-methoxybenzyl ethers to give di rectly the corresponding t-butyldimethylsilyl ethers in high yields th us affording an expedient way to replace the benzyl ether-type protect ive group with the silyl ether-type one.