ALPHA-STEREOSELECTIVE TANDEM ADDITIONS TO (ORTHO-METHOXYSTYRENE) CHROMIUM TRICARBONYL

Authors
DAVIES SG FURTADO OMLR HEPWORTH D LOVERIDGE T
Citation
Sg. Davies et al., ALPHA-STEREOSELECTIVE TANDEM ADDITIONS TO (ORTHO-METHOXYSTYRENE) CHROMIUM TRICARBONYL, Synlett, (1), 1995, pp. 69-70
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
1
Year of publication
1995
Pages
69 - 70
Database
ISI
SICI code
0936-5214(1995):1<69:ATAT(C>2.0.ZU;2-8
Abstract
Homochiral (1'R)-(+)-(ortho-methoxystyrene) chromium tricarbonyl under goes a completely alpha-stereoselective tandem beta-nucleophilic, alph a-electrophilic addition sequence with t-butyl lithium and methyl iodi de to generate, after decomplexation, homochiral (2R)-(+)-2-(ortho-ani syl)-4,4-dimethylpentane.