TRIBUTYLCHLOROSTANNANE AS LEWIS-ACID IN THE REGIOSELECTIVE REDUCTIVE CLEAVAGE OF KETALS

Citation
A. Srikrishna et R. Viswajanani, TRIBUTYLCHLOROSTANNANE AS LEWIS-ACID IN THE REGIOSELECTIVE REDUCTIVE CLEAVAGE OF KETALS, Synlett, (1), 1995, pp. 95-96
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
09365214
Issue
1
Year of publication
1995
Pages
95 - 96
Database
ISI
SICI code
0936-5214(1995):1<95:TALITR>2.0.ZU;2-P
Abstract
A regioselective reductive demethoxylation of dimethyl and mixed ketal s, using sodium cyanoborohydride in the presence of a catalytic amount of tributylchlorostannane as Lewis acid in refluxing tert-butanol is described.