CARBENOIDS FROM PRIMARY ALKYL CHLORIDES BY HETEROATOM-ASSISTED METALATION

Authors
CLAYDEN J JULIA M
Citation
J. Clayden et M. Julia, CARBENOIDS FROM PRIMARY ALKYL CHLORIDES BY HETEROATOM-ASSISTED METALATION, Synlett, (1), 1995, pp. 103-104
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
1
Year of publication
1995
Pages
103 - 104
Database
ISI
SICI code
0936-5214(1995):1<103:CFPACB>2.0.ZU;2-1
Abstract
3-Chloroalkyl ethers can be deprotonated alpha to the chlorine atom at low temperatures, and the resulting carbenoids trapped intramolecular ly to give alpha-halosilanes or cyclopropanes.