Js. Banait et al., ELECTROCHEMICAL REACTIONS AT SACRIFICIAL ELECTRODES .8. SYNTHESIS OF ALUMINUM ALKOXIDES AND THEIR COORDINATION-COMPOUNDS, Journal of the Indian Chemical Society, 71(9), 1994, pp. 543-546
Aluminium alkoxides, Al(OR)3 (R = methyl, ethyl, n-propyl, n-butyl and
n-amyl groups), have been synthesised by the direct electrochemical t
echnique. Though these alkoxides do not form coordination compounds wh
en refluxed with 1,10-phenanthroline, yet coordination compounds of al
l these alkoxides have been synthesised with 1,10-phenanthroline by th
e electrochemical method. The products have been characterised by elem
ental analysis and infrared spectral data. Current efficiencies of all
these systems are quite high.