T. Kasuga et al., PREPARATION OF POROUS CERAMICS WITH CALCIUM METAPHOSPHATE FIBER SKELETON FOR BIOMEDICAL USE, Journal of the American Ceramic Society, 78(1), 1995, pp. 245-247
High-strength calcium metaphosphate fibers for biomedical applications
are extracted from crystallized products of calcium ultraphosphate gl
asses by aqueous leaching. In the present work, new types of porous ce
ramics with a skeleton composed of the crystalline fibers are prepared
by heating the fibrous products extracted. The fibers in the ceramic
are interlinked to each other by glassy phases formed during the heati
ng. This porous material has a large porosity of >60%. The surface of
the skeleton can be successfully converted into new calcium phosphate
phases such as apatite by heating the porous material treated with a m
olten salt mixture of CaCl2Ca(NO3)(2).