APPLICATION OF F-19 NMR-SPECTROSCOPY TO THE STUDY OF EQUILIBRIUM DYNAMICS OF URANYL(2-FLUORIDE COMPLEXES())

Authors
SZABO Z GLASER J
Citation
Z. Szabo et J. Glaser, APPLICATION OF F-19 NMR-SPECTROSCOPY TO THE STUDY OF EQUILIBRIUM DYNAMICS OF URANYL(2-FLUORIDE COMPLEXES()), Magnetic resonance in chemistry, 33(1), 1995, pp. 20-26
Citations number
28
Categorie Soggetti
Spectroscopy,Chemistry
Journal title
Magnetic resonance in chemistry → ACNP
ISSN journal
07491581
Volume
33
Issue
1
Year of publication
1995
Pages
20 - 26
Database
ISI
SICI code
0749-1581(1995)33:1<20:AOFNTT>2.0.ZU;2-V
Abstract
One- and two-dimensional magnetization-transfer F-19 NMR methods were applied in a quantitative study of the fluoride exchange for uranyl(2)-fluoride complexes in aqueous solution. The applicability of these t echniques and the classical lineshape analysis is discussed, and the q uality of the results (rate constants and relaxation rates) obtained b y the three methods is compared.