SOLAR PHOTOCHEMISTRY - PHOTOOXIDATION OF HYDROGEN-SULFIDE

Authors
WOHRLE D SPILLER W SCHNEIDER G SCHULZEKLOFF G STARK J
Citation
D. Wohrle et al., SOLAR PHOTOCHEMISTRY - PHOTOOXIDATION OF HYDROGEN-SULFIDE, Journal of Information Recording Materials, 21(5-6), 1994, pp. 481-485
Citations number
22
Categorie Soggetti
Photographic Tecnology","Material Science
Journal title
Journal of Information Recording Materials → ACNP
ISSN journal
08630453
Volume
21
Issue
5-6
Year of publication
1994
Pages
481 - 485
Database
ISI
SICI code
0863-0453(1994)21:5-6<481:SP-POH>2.0.ZU;2-T
Abstract
Hydrogen sulfide is efficiently oxidized to sulfate in aqueous solutio n in the presence of water soluble Zn and Al phthalocyanines 2-4 as ph otocatalysts by irradiation with visible light (model reaction for sol ar radiation). Co phthalocyanine 1 exhibits similar activity in the da rk and under irradiation with formation of thiosulfate as oxidation pr oduct. Singlet dioxygen is involved in the photooxidation process.