KINETIC SPECTROPHOTOMETRIC DETERMINATION OF HYDRAZINE

Authors
SAFAVI A ENSAFI AA
Citation
A. Safavi et Aa. Ensafi, KINETIC SPECTROPHOTOMETRIC DETERMINATION OF HYDRAZINE, Analytica chimica acta, 300(1-3), 1995, pp. 307-311
Citations number
22
Categorie Soggetti
Chemistry Analytical
Journal title
Analytica chimica acta → ACNP
ISSN journal
00032670
Volume
300
Issue
1-3
Year of publication
1995
Pages
307 - 311
Database
ISI
SICI code
0003-2670(1995)300:1-3<307:KSDOH>2.0.ZU;2-9
Abstract
A sensitive kinetic method for determining low levels of hydrazine has been described. The method is based on the measurement of the rate of the reaction between hydrazine and Mo(VI) in the presence of hydrochl oric acid. The redox reaction was monitored spectrophotometrically at 710 nm. The variable-time and fixed-time methods were used. The calibr ation graph was linear for hydrazine concentrations of 1.0 X 10(-4)-1. 4 X 10(-2) M, using the fixed-time method of analysis. The method is s imple, rapid, precise, sensitive and widely applicable.