Cl. Riediger et Jd. Bloch, DEPOSITIONAL AND DIAGENETIC CONTROLS ON SOURCE-ROCK CHARACTERISTICS OF THE LOWER JURASSIC NORDEGG MEMBER, WESTERN CANADA, Journal of sedimentary research. Section A, Sedimentary petrology and processes, 65(1), 1995, pp. 112-126
Petrographic, mineralogical, and bulk-geochemical (XRD, XRF, and Rock-
Eval) data indicate that depositional and early diagenetic processes w
ere the principal controls on the organic and inorganic characteristic
s of the Lower Jurassic ''Nordegg Member'' source rock, This unit comp
rises organic-rich, calcareous mudstones to marlstones and marry limes
tones that were deposited in a predominantly anoxic, hypersaline, sill
ed marine basin during two transgressive-regressive (T-R) events, Sedi
ments deposited during marine transgression have a higher content of c
arbonate (calcite and dolomite) and organic matter, Fe (mainly as pyri
te) content varies inversely with carbonate content. The basal ''Norde
gg Member'' is phosphatic with stratiform apatite laminae and phosphat
ic nodules, Early diagenetic phosphatogenesis was probably mediated by
bacteria under variably dysoxic conditions during the initial transgr
essive event, Regressive parts of T-R cycles are expressed as an incre
ase in abundance of silicate (quartz, illite, kaolinite, and minor K-f
eldspar) and lower organic carbon contents. Deposition of abundant mar
ine organic matter fueled vigorous bacterial reduction of sulfate and
almost total bacterial reworking of the sedimented organic matter, res
ulting in significant production of reduced sulfur species and predomi
nantly amorphous kerogen, Pyrite formation was ubiquitous but limited
by the abundance of Fe, Where Fe contents fell below 3 wt %, excess su
lfides were incorporated into the kerogen, This process resulted in th
e early diagenetic formation of the sulfur-rich kerogen (Type I/II-S)
that typifies the ''Nordegg'', Thus Fe availability in the depositiona
l environment exerted an important control on the amount of S availabl
e for incorporation into the kerogen. Furthermore, content of organic
S increases with increasing Hydrogen Index, indicating the importance
of type and reactivity of organic matter on the extent of incorporatio
n of sulfur into the kerogen during early diagenesis.