The positron beam technique is shown to be a sensitive indicator of th
e presence of arsenic within the grain boundaries of poly-silicon. Var
iable-energy positron beam and secondary-ion mass spectrometry studies
have been performed on As+-implanted pre-amorphized Si samples as a f
unction of dose and rapid thermal anneal temperature. Positron trappin
g within negatively-charged grain boundaries of the recrystallized pol
y-Si is observed, resulting in a similar to 2% elevation in the Dopple
r-broadening S lineshape parameter value. Infusion of As+-ions into th
e grain boundaries passivates the charge and reduces their specific po
sitron-trapping rate.