O. Penrose et Pv. Coveney, IS THERE A CANONICAL NONEQUILIBRIUM ENSEMBLE, Proceedings - Royal Society. Mathematical and physical sciences, 447(1931), 1994, pp. 631-646
We consider a simple dynamical system, related to the baker's transfor
mation. This 'pastry-cook's transformation', operating in a space cons
isting of two congruent squares, is performed by cutting both squares
into q vertical slices, squashing each to 1/q of its previous height,
rearranging the squashed slices to make two new squares as in the bake
r's transformation, and finally interchanging the lowest p slices betw
een the two squares. This transformation approximately mimics the ergo
dic behaviour of a particle in a vessel consisting of two compartments
separated by a diaphragm with a small hole in it occupying a fraction
pig of the total surface area of either compartment. We show, for lar
ge classes of initial ensembles and 'observable' dynamical variables,
that the expectation value of any such dynamical variable at large tim
es t is asymptotically the same as it would be in a 'canonical non-equ
ilibrium ensemble' in which expectations are defined by E(g)[phi] = E
(eq)[phi] + <h(x),g> <h(y),phi>. Here E(g) denotes an expectation tak
en with respect to the initial phase-space density g, E(eq) denotes an
expectation in the equilibrium ensemble, h(x), h(y) are certain linea
r functionals, and phi = U-t f, where U is the evolution operator and
f is an observable.