Two non-linear bead and spring models are considered for the Brownian
dynamics simulation of the behaviour of polymer chains in a dilute sol
ution under shear or elongational flow. One of them is the HYBRID mode
l whose springs are Hookean at low elongation, and beyond some spring
length they follow a Morse potential with a given dissociation energy.
This model is suitable for studying polymer fracture in strong flows.
In this paper we describe the model and check that it has the proper
behaviour in the two regions. The second model is a chain of finitely
extensible, non-linear elastic (FENE) springs. Our simulations show se
veral features of the FENE model that agree well with observation. In
shear flow, the deformation of the FENE chain at high shear rate devia
tes from the square law followed at low shear, in agreement with some
experiments. The model also predicts the typical shear-thinning, non-N
ewtonian behaviour of the shear viscosity. In elongational flows, the
variation of the chain properties with the elongation rate shows a rat
her sharp increase at some critical rate that is reminiscent of the so
-called coil-stretch transition.