EFFICIENT SYNTHESIS OF AMINONAPHTHOQUINONES AND AZIDOBENZOHYDROQUINONES - MECHANISTIC CONSIDERATIONS OF THE REACTION OF HYDRAZOIC ACID WITHQUINONES, AN OVERVIEW

Citation
Ea. Couladouros et al., EFFICIENT SYNTHESIS OF AMINONAPHTHOQUINONES AND AZIDOBENZOHYDROQUINONES - MECHANISTIC CONSIDERATIONS OF THE REACTION OF HYDRAZOIC ACID WITHQUINONES, AN OVERVIEW, Journal of organic chemistry, 62(1), 1997, pp. 6-10
Citations number
56
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
00223263
Volume
62
Issue
1
Year of publication
1997
Pages
6 - 10
Database
ISI
SICI code
0022-3263(1997)62:1<6:ESOAAA>2.0.ZU;2-7
Abstract
Parameters useful to predict and control the reaction outcome of conju gate addition of hydrazoic acid to quinones have been studied, and the optimum conditions for the efficient synthesis of aminonaphthoquinone s and azidobenzohydroquinones are reported. The application of this re action for the efficient formal synthesis of dephostatin is also prese nted.