ARYL NITRILE OXIDE CYCLOADDITION REACTIONS IN THE PRESENCE OF BAKERS-YEAST AND BETA-CYCLODEXTRIN

Citation
Cj. Easton et al., ARYL NITRILE OXIDE CYCLOADDITION REACTIONS IN THE PRESENCE OF BAKERS-YEAST AND BETA-CYCLODEXTRIN, Tetrahedron letters, 36(4), 1995, pp. 629-632
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
36
Issue
4
Year of publication
1995
Pages
629 - 632
Database
ISI
SICI code
0040-4039(1995)36:4<629:ANOCRI>2.0.ZU;2-F
Abstract
Contrary to recent reports, baker's yeast is not required for reaction s of nitrile oxides with either ethyl cinnamate or 4-vinylpyridine to give isoxazolines. beta-Cyclodextrin may alter the ratio of isomers is olated from the reactions of the cinnamate but only at concentrations of reactants much lower than those reported, and this effect is most l ikely due to selective product complexation rather than selective prod uct formation.