S. Valeri et al., PRIMARY-BEAM DIFFRACTION MODULATED ELECTRON-EMISSION (PDMEE) FOR SURFACE STRUCTURAL-ANALYSIS, Surface and interface analysis, 21(12), 1994, pp. 852-856
Scattering interference of primary exciting electrons leads to a depen
dence of the Auger emission intensity on the beam incidence angle. For
beam energy in the kiloelectron-volt range, maxima in the Auger yield
occur when the primary beam is aligned with low-index crystal axes, t
herefore the Auger angular intensity distribution directly reflects th
e symmetries and the degree of local order. We investigated the potent
ial for this effect, primary-beam diffraction modulated electron emiss
ion (PDMEE) to be used for surface structural characterization, in com
parison with the Auger electron/photoelectron diffraction (AED/PD) tec
hnique. The angular intensity distributions of both low and high kinet
ic energy Auger electrons were measured on both GaAs and InP (110) sur
faces. We show, by using highly collimated energetic electron beams, t
hat the angular resolution is significantly improved in PDMEE with res
pect to AED/PD. Unlike the AED/PD case, the angular intensity distribu
tion is independent of the kinetic energy of the Auger electrons, ther
efore low-energy, surface-sensitive electrons also directly reflect cr
ystal symmetries, owing also to the fact that the specific momentum ch
aracter of the Auger electrons can be neglected. Anisotropy in the int
ensity angular distribution as large as 70% was measured, comparable t
o AED/PD anisotropy values. Both a retarding field (low-energy electro
n diffraction optics) and a dispersion field cylindrical mirror analys
er were used for PDMEE analysis, and instrumental performances are dis
cussed comparatively.