6 MEMBERED RING-OPENING OF ISOPROPYLIDENE MALONATE DERIVATIVES - SYNTHESIS OF ALPHA,BETA-UNSATURATED THIOARYL AND SELENOARYL CARBOXYLIC ESTERS

Authors
Citation
Wl. Bao et Ym. Zhang, 6 MEMBERED RING-OPENING OF ISOPROPYLIDENE MALONATE DERIVATIVES - SYNTHESIS OF ALPHA,BETA-UNSATURATED THIOARYL AND SELENOARYL CARBOXYLIC ESTERS, Synthetic communications, 25(2), 1995, pp. 143-148
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
25
Issue
2
Year of publication
1995
Pages
143 - 148
Database
ISI
SICI code
0039-7911(1995)25:2<143:6MROIM>2.0.ZU;2-Z
Abstract
Six membered rings of isopropylidene malonate derivatives were opened by aryl thiolate anions and aryl selenolate anions which were produced through reductive cleavage of diaryl disulfides and diaryl diselenide s with SmI2, and the substituted propenoic acid selenoaryl and thioary l esters were synthesized.