FACILE TANDEM MICHAEL-ADDITION RETRO-DIECKMANN REACTION OF CYCLIC BETA-KETOESTERS - ONE-POT PREPARATION OF POLYFUNCTIONALIZED ACYCLIC DERIVATIVES

Citation
Mh. Filippini et J. Rodriguez, FACILE TANDEM MICHAEL-ADDITION RETRO-DIECKMANN REACTION OF CYCLIC BETA-KETOESTERS - ONE-POT PREPARATION OF POLYFUNCTIONALIZED ACYCLIC DERIVATIVES, Synthetic communications, 25(2), 1995, pp. 245-252
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
25
Issue
2
Year of publication
1995
Pages
245 - 252
Database
ISI
SICI code
0039-7911(1995)25:2<245:FTMRRO>2.0.ZU;2-K
Abstract
A facile base promoted tandem Michael addition-retro Dieckmann reactio n leading to polyfunctionalized acyclic derivatives is observed by con densation of beta-ketoesters with alpha,beta-unsaturated electrophiles in methanol.