THE CHEMOSELECTIVE CLEAVAGE OF ACYLTHIOARYLTHIOACETALS WITH TRIBUTYLTIN HYDRIDE

Authors
GAREAU Y ZAMBONI R GAUTHIER JY BERNSTEIN MA
Citation
Y. Gareau et al., THE CHEMOSELECTIVE CLEAVAGE OF ACYLTHIOARYLTHIOACETALS WITH TRIBUTYLTIN HYDRIDE, Synthetic communications, 25(2), 1995, pp. 259-267
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
25
Issue
2
Year of publication
1995
Pages
259 - 267
Database
ISI
SICI code
0039-7911(1995)25:2<259:TCCOAW>2.0.ZU;2-P
Abstract
Acylthioarylthioacetals are cleaved selectively by tributyltin hydride /AIBN affording thioacyls radicals, which can react with tethered carb on-carbon double or triple bond to form functionalized cyclopentanes.