RADICAL STEPS IN THE REACTIONS OF ORGANOMETALLIC COMPOUNDS WITH 2-METHYL-2-NITROSOPROPANE - EXPERIMENTAL EVALUATION OF THE VALIDITY OF THE NITROXYL METHOD FOR INVESTIGATIONS OF HOMOLYTIC REACTIONS OF ORGANOMETALLIC COMPOUNDS

Authors
GRISHIN DF CHERKASOV VK DODONOV VA
Citation
Df. Grishin et al., RADICAL STEPS IN THE REACTIONS OF ORGANOMETALLIC COMPOUNDS WITH 2-METHYL-2-NITROSOPROPANE - EXPERIMENTAL EVALUATION OF THE VALIDITY OF THE NITROXYL METHOD FOR INVESTIGATIONS OF HOMOLYTIC REACTIONS OF ORGANOMETALLIC COMPOUNDS, Russian chemical bulletin, 43(5), 1994, pp. 862-866
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
5
Year of publication
1994
Pages
862 - 866
Database
ISI
SICI code
1066-5285(1994)43:5<862:RSITRO>2.0.ZU;2-Q
Abstract
Radical adducts formed in the reactions of organometallic compounds of group II-V elements and of some organochromium and organoiron compoun ds with 2-methyl-2-nitrospropane and phenyl(tert-butyl)nitrone were st udied by ESR. Nitroso compounds and nitrones can be used as selective spin traps for investigations of homolytic reactions involving organom etallic compounds.