REACTION OF (C6F5)(2)HGEGEH(C6F5)(2) WITH TRIETHYLBISMUTH - MOLECULAR-STRUCTURE OF [(C6F5)(2)GE]4BI2

Authors
PANKRATOV LV ZAKHAROV LN BOCHKOVA RI FUKIN GK STRUCHKOV YT
Citation
Lv. Pankratov et al., REACTION OF (C6F5)(2)HGEGEH(C6F5)(2) WITH TRIETHYLBISMUTH - MOLECULAR-STRUCTURE OF [(C6F5)(2)GE]4BI2, Russian chemical bulletin, 43(5), 1994, pp. 867-870
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
5
Year of publication
1994
Pages
867 - 870
Database
ISI
SICI code
1066-5285(1994)43:5<867:RO(WT->2.0.ZU;2-5
Abstract
The reaction of (C6F5)(2)HGeGeH(C6F5) with triethylbismuth affords a n ew polynuclear germylbismuth derivative, [(C6F5)(2)Ge]Bi-4(2) (1) The metal framework of molecule 1 has the form of a gable roof built by tw o central Bi atoms and four peripheral Ge atoms with covalent Bi-Bi bo nds [3.045(3) Angstrom], Bi-Ge [2.724(5)-2.755(5) Angstrom] and Ge-Ge [2.444(6), 2.465(6) Angstrom].